Lanthanide-potassium wheels |
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Authors: | Gamer Michael T Roesky Peter W |
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Institution: | Institut für Chemie, Freie Universit?t Berlin, Fabeckstrasse 34-36, 14195 Berlin, Germany. |
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Abstract: | Mixed potassium-lanthanide wheel-shaped-structured, hexanuclear coordination oligomers of composition (eta5-C5H5)Ln(NPh2)2{N(PPh2)2}2K2(THF)4]2 (Ln = Er (1a), Yb (1b)) and an octanuclear coordination polymer of composition (eta5-C5H5)Sm(NPh2)2{N(PPh2)2}K]infinity (2) were synthesized. All presented compounds can be obtained in moderate yields in a one-pot procedure, in which the potassium salts KNPh2 and K(THF)(n)N(PPh2)2] as well as NaC5H5 are reacted with anhydrous samarium, erbium, and ytterbium trichloride in THF. |
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