Electrolytic coloration and spectral properties of hydroxyl-doped potassium chloride single crystals |
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Authors: | Hongen Gu Yanru Wu |
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Affiliation: | a Department of Physics, Tianjin University, Tianjin 300072, PR China b School of Basic Medical Science, Hebei Medical University, Shijiazhuang 050017, PR China |
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Abstract: | Hydroxyl-doped potassium chloride single crystals are colored electrolytically at various temperatures and voltages using a pointed cathode and a flat anode. Characteristic OH− spectral band is observed in the absorption spectrum of uncolored single crystal. Characteristic O−, OH−, U, V2, V3, O2−-Va+, F, R2 and M spectral bands are observed simultaneously in absorption spectra of colored single crystals. Current-time curve for electrolytic coloration of hydroxyl-doped potassium chloride single crystal and its relationship with electrolytic coloration process are given. Production and conversion of color centers are explained. |
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Keywords: | Potassium chloride single crystal Electrolytic coloration Color center |
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