| 含有POSS的复合型质子交换膜的制备及性能 |
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| 引用本文： | 李雪峰,宋洋,朱明,刘佰军,姜振华.含有POSS的复合型质子交换膜的制备及性能[J].高等学校化学学报,2011,32(8):1670-1672. |
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| 作者姓名： | 李雪峰 宋洋 朱明 刘佰军 姜振华 |
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| 作者单位： | 吉林大学麦克德尔米德实验室, 长春 130012 |
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| 基金项目： | 国家自然科学基金(批准号:50973040); 吉林省科技厅-国际合作项目(批准号:20100706)资助 |
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| 摘 要： | 本文以一种具有含萘结构的磺酸化聚芳醚酮作为主体材料, 采用具有相似化学结构的含萘、 醚和酮结构的聚甲亚胺作为增强组分, 通过溶胶-凝胶的方法在复合膜中引入提高质子传输能力的酸功能化聚倍半硅氧烷(POSS-SO3H), 制备新型的三元复合型质子交换膜, 并对其微结构和性能进行了研究.
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| 关 键 词： | 质子交换膜 燃料电池 聚芳醚酮 复合 |
| 收稿时间： | 2011-03-15 |
Preparation and Properties of the POSS-containing Composites as Proton Exchange Membranes |
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| LI Xue-Feng,SONG Yang,ZHU Ming,LIU Bai-Jun,JIANG Zhen-Hua.Preparation and Properties of the POSS-containing Composites as Proton Exchange Membranes[J].Chemical Research In Chinese Universities,2011,32(8):1670-1672. |
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| Authors: | LI Xue-Feng SONG Yang ZHU Ming LIU Bai-Jun JIANG Zhen-Hua |
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| Institution: | Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China |
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| Abstract: | A naphthylene-containing sulfonated polyaryletherketone(SPAEK) was synthesized as a matrix.A polyazomethine having naphthylene,ether and ketone linkages(PAM) was selected as a molecular-enhanced component.Aimed at improving the properties,a ternary-composite membrane was constructed by incorporating sulfonic acid-functionalized polysilsesquioxane through a sol-gel processing.The morphology of the membranes was studied by SEM.Compared with plain SPAEK and SPAEK/PAM blend,the ternary-composite membranes show ... |
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| Keywords: | Proton exchange membrane Fuel cell Polyaryletherketone Composite |
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