Correlation between Molecular Structure of Ferrocene Derivative and Impact Sensitivity of Fine‐AP/Ferrocene Derivative Mixture |
| |
| Authors: | Lei Deng Benzheng Jiang Wei Zhang Jun Yang Tong Bao Yan Yu Xiaoqiang Li Xing Zhou |
| |
| Institution: | 1. School of Aerospace Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073, China;2. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
| |
| Abstract: | On the basis of investigation of molecular structure characteristics of model ferrocene derivatives, the correlation between stability and molecular structure of double‐core ferrocene derivatives (DFDs) was studied. Then, the relation of stability of DFDs and impact sensitivity of fine‐AP/DFD mixtures was investigated. The results showed that the DFDs with methylene bridge group were more stable than those with methylethylidene bridge group. The stability order of the five DFDs was DEFM>EDFM≈BDFM>GFP>TBPF. The impact sensitivities of the fine‐AP/DFD mixtures were in inverse proportion to the stabilities of the DFDs. |
| |
| Keywords: | double‐core ferrocene derivatives molecular structure stability impact sensitivity |
|
|
