Thioether glycidyl resins. VI. Reaction products of opening of oxirane ring of phenylthioetherglycidyl resin and of some derivatives under the influence of temperature |
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| Authors: | W&#x;adys&#x;aw Charmas Wawrzyniec Podko cielny Joachim Brunn |
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| Institution: | Władysław Charmas,Wawrzyniec Podkościelny,Joachim Brunn |
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| Abstract: | The process of oxirane ring opening of thioether glycidyl resins under various temperatures has been described. Reaction rate constants (k) and the activaton parameters (Eα, ΔH*, ΔS*) for epoxy group loss of 1,2-epoxy-3-(phenylthio)propane, 1,2-epoxy-3-(p-tolythio)propane, and 1,2-epoxy-3-(p-chloro-phenylthio)propane using classical kinetic methods were determined. The reaction products were separated and analyzed by means of chromatography and the structure of the compounds was determined by means of the spectral analyses: IR, 1H-NMR, and 13C-NMR |
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