抗癌中草药冬凌草甲素的吸附伏安行为 |
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引用本文: | 袁利杰,张玉峰,冶保献.抗癌中草药冬凌草甲素的吸附伏安行为[J].化学研究,2004,15(4):30-33. |
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作者姓名: | 袁利杰 张玉峰 冶保献 |
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作者单位: | 郑州大学化学系,河南,郑州,450052;郑州市环境保护监测中心站,河南,郑州,450007 |
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基金项目: | 河南省自然科学基金资助课题(0211020400) |
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摘 要: | 研究了抗癌药物冬凌草甲素在悬汞电极上的电化学行为。在NaAc NaOH(pH=7.8)的缓冲溶液中,冬凌草甲素有一受吸附控制的还原峰,峰电位为-1.150V,其电极反应过程是单电子转移,传递系数α为0.834,电荷传递表观速率常数KS为2.26s-1,初步探讨了其可能的电极反应机理.
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关 键 词: | 冬凌草甲素 悬汞电极 循环伏安法 |
文章编号: | 1008-1011(2004)04-0030-04 |
修稿时间: | 2004年6月28日 |
Adsorptive Voltammetry Behavior of an Antitumor Herbal Drug Idinonine |
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Abstract: | The electrochemical behavior of idinonine (IDN) on the hanging mercury electrode has been investigated. In acetic acid buffer solution(pH=7.8), an adsorption-driven reduction peak of idinonine is obtained with the peak potential at -1.150V(vs.SCE), the electrode process involves single electron transfer reaction with α=0.834 and K_S=2.26 s~-1. The mechanism of the reaction is discussed simply. |
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Keywords: | idinonine hanging mercury electrode cyclic voltammetry |
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