Preparation and electrochemistry of one-dimensional nanostructured MnO2/PPy composite for electrochemical capacitor |
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Authors: | Juan Li Li Cui |
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Institution: | a School of Science, Xi’an Jiaotong University, Xi’an 710049, China b College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China c College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China |
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Abstract: | One-dimensional nanostructured manganese dioxide/polypyrrole (MnO2/PPy) composite was prepared by in situ chemical oxidation polymerization of pyrrole in the host of inorganic matrix of MnO2, using complex of methyl orange (MO)/FeCl3 as a reactive self-degraded soft-template. The morphology and structure of the composite were characterized by infrared spectroscopy (IR) X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that the MnO2/PPy composite consists of α-MnO2 and PPy with nanotube-like structure. Electrochemical properties of the composite demonstrated the material showed good electrochemical reversibility after 500 charge-discharge cycles in the potential range of −0.4 to 0.6 V, the tube-like nanocomposite has the potential application in electrochemical capacitor. |
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Keywords: | Soft-template One-dimensional nanostructure Manganese dioxide Polypyrrole Electrochemical capacitor |
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