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A new route to metallacycloalkanes |
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| Authors: | Dralle Katja Jaffa Nastassia L le Roex Tanya Moss John R Travis Susan Watermeyer Nicholas D Sivaramakrishna Akella |
| Affiliation: | Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa. |
| Abstract: | Reaction of the bis-alkenyl complex cis-[Pt(PPh3)2(CH2CH2CH=CH2)2] with Grubbs 1st generation catalyst gives, in high yield, the metallacycloalkene cis-[Pt(PPh3)2(CH2CH2CH=CHCH2CH2)], which can be hydrogenated to the metallacycloalkane cis-[Pt(PPh3)2(CH2)6]. |
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