Study of the Thermal Decompositions on N,N-Dialkyl-N'-Benzoylthiourea Complexes of Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III) |
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| Authors: | Merdivan M Karipcin F Kulcu N Aygun R S |
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| Institution: | (1) Department of Chemistry, Balikesir University, Balikesir, Turkey;(2) Department of Chemistry, Suleyman Demirel University, Isparta, Turkey;(3) Department of Chemistry, Mersin University, Mersin, Turkey;(4) Department of Chemistry, Middle East Technical University, Ankara, Turkey |
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| Abstract: | The thermal decompositions of the complexes of N,N-dialkyl-N'-benzoylthioureas with Cu(II), Ni(II), Pd(II), Pt(II), Cd(II), Ru(III) and Fe(III) were studied by TG and DTA techniques. These metal complexes decompose in two stages: elimination of dialkylbenzamide, and total decomposition to metal sulphides or metals. The influence of the alkyl substituents in these benzoylthiourea chelates on the thermal behaviour of the metal complexes was investigated.This revised version was published online in November 2005 with corrections to the Cover Date. |
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| Keywords: | metal complexes N N-dialkyl-N'-benzoylthiourea thermal decomposition |
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