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One‐Pot Synthesis and Electrocatalytic Properties of Pd@Pt Core‐Shell Nanocrystals with Tailored Morphologies
Authors:Yena Kim  Young Wook Lee  Minjune Kim  Prof?Dr Sang Woo Han
Institution:1. Department of Chemistry and KI for the NanoCentury, KAIST, Daejeon 305‐701 (Korea), Fax: (+82)?42‐350‐2810;2. Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Daejeon 305‐701 (Korea)
Abstract:Pd@Pt core‐shell nanocrystals consisting of well‐defined Pd nanocube cores and dendritic Pt shells were prepared by a new facile aqueous one‐pot synthetic method. The prepared Pd@Pt nanocrystals exhibited efficient catalytic activity and stability toward methanol electrooxidation, and their catalytic function was highly dependent on their Pt shell thickness due to the different synergism between Pt and Pd.
Keywords:core‐shell  electrocatalysis  nanocrystals  palladium  platinum
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