Physicochemical features of the formation of siliceous porous mesophases |
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Authors: | V. N. Romannikov V. B. Fenelonov A. Yu. Derevyankin |
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Affiliation: | 1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation
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Abstract: | The formation of siliceous mesoporous mesophase materials (SiO2-MMM) prepared by precipitation of soluble forms of SiO2 with alkyltrimethylalkylammonium bromide C n TMABr (n=12, 14, 16, 18 is the number of carbon atoms in the alkyl chain) was investigated. An increase in then value has no influence on the mechanism of formation of SiO2-MMM but causes an increase in the size and volume of mesopores with the mesopore specific surface area and wall thickness remaining virtually constant. |
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