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Energetics of lead(II), cadmium(II) and zinc(II) complexes with amino acids
Authors:Manuel A V Ribeiro da Silva  Luís M N B F Santos  Ana C P Faria  Filipa S A Sistelo
Institution:1.Department of Chemistry, Faculty of Science, Centro de Investiga??o em Química,University of Porto,Porto,Portugal
Abstract:
The molar heat capacity and the standard (p 0 = 0.1 MPa) molar enthalpies of formation of the crystalline of bis(glycinate)lead(II), Pb(gly)2; bis(dl-alaninate)lead(II), Pb(dl-ala)2; bis(dl-valinate)lead(II), Pb(dl-val)2; bis(dl-valinate)cadmium(II), Cd(dl-val)2 and bis(dl-valinate)zinc(II), Zn(dl-val)2, were determined, at T = 298.15 K, by differential scanning calorimetry, and high precision solution-reaction calorimetry, respectively. The standard molar enthalpies of formation of the complexes in the gaseous state, the mean molar metal–ligand dissociation enthalpies, M(II)–amino acid, \( \langle D_{\text{m}} \rangle \)(M–L), were derived and compared with analogous copper(II)–ligand and nickel(II)–ligand.θθ
M(II)–amino acid \( \Updelta_{\text{f}} H_{\text{m}}^{\text{o}} \)(cr)/kJ mol?1
Bis(glycinate)lead(II), Pb(gly)2 ?998.9 ± 1.9
Bis(dl-alaninate)lead(II), Pb(ala)2 ?1048.7 ± 1.8
Bis(dl-valinate)lead(II), Pb(val)2 ?1166.3 ± 2.5
Bis(dl-valinate)cadmium(II), Cd(val)2 ?1243.7 ± 2.7
Bis(dl-valinate)zinc(II), Zn(val)2 ?1306.1 ± 2.3
Keywords:
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