| [Pb2(TNR)(NO3)2(H2O)]的制备和晶体结构研究 |
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| 引用本文： | 张同来,杨永明,张建国,邵兵,杨利,郁开北.[Pb2(TNR)(NO3)2(H2O)]的制备和晶体结构研究[J].无机化学学报,2002,18(3):305-308. |
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| 作者姓名： | 张同来 杨永明 张建国 邵兵 杨利 郁开北 |
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| 作者单位： | 1. 北京理工大学机电工程学院,北京,100081
2. 中科院成都分院分析测试中心,成都,610041 |
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| 摘 要： | Pb2(TNR)(NO3)2(H2O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb2(TNR)(NO3)2(H2O)was determined by single crystal diffraction analysis. The crystal is triclinic, space group P1 with crystal parameters a=0.7279(2)nm,b=1.0698(2)nm,c=1.0738(2)nm;α=86.82(1)°,β=89.52(2)°,γ=83.50(2)°;V=0.8295(3)nm3,Z=2,Dc=3.201g·cm-3, F(000)=716. The final R value is 0.0358.In the crystal structure, one lead ion was represented by nine coor-dination geometry; the other was showed as ten coordination geometry.
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| 关 键 词： | 铅配合物 制备 晶体结构 |
Preparation and Molecular Structure of [Pb2(TNR)(NO3)2(H2O)] |
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| ZHANG Tong-Lai,YANG Yong-Ming,ZHANG Jian-Guo,SHAO Bing,YANG Li and YU Kai-Bei.Preparation and Molecular Structure of [Pb2(TNR)(NO3)2(H2O)][J].Chinese Journal of Inorganic Chemistry,2002,18(3):305-308. |
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| Authors: | ZHANG Tong-Lai YANG Yong-Ming ZHANG Jian-Guo SHAO Bing YANG Li and YU Kai-Bei |
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| Institution: | College of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,College of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,College of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,College of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,College of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081 and Analysis and Measurement Center, China Science Academy Chengdu Branch, Chengdu 610041 |
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| Abstract: | |
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| Keywords: | lead complex preparation crystal structure |
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