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Molecular Exchanging Energy of Anionic/Cationic Surfactants System on the Surface of Solution
引用本文:DongYangHUANG XiZhangYI ZhengWuWANG. Molecular Exchanging Energy of Anionic/Cationic Surfactants System on the Surface of Solution[J]. 中国化学快报, 2003, 14(10): 1077-1080
作者姓名:DongYangHUANG XiZhangYI ZhengWuWANG
作者单位:[1]MedicalSchoolofShantouUniversity,Shantou515031 [2]InstituteofTheoreticalChemistry,ShandongUniversity,Jinan250100
基金项目:国家自然科学基金,Governor Foundation of Guizhou Province for their financial supports 
摘    要:
In order to study synergism of the mixed surfactants system with molecular exchanging energy ( ε ), the Lennard-Jones formula has been firstly introduced to evaluate the ε of the mixed system, CH3(CH2)nOSO 3^- /CH3(CH2)nN^ (CH3)3, directly from their molecular structure. The comparison of the calculated and the observed results showed that this method is practical.

关 键 词:分子交换能 阴离子/阳离子表面活性剂系统 溶液界面 立体晶体模型 分子结构

Molecular Exchanging Energy of Anionic/Cationic Surfactants System on the Surface of Solution
Zheng Wu WANG,Dong Yang HUANG,Xi Zhang YI. Molecular Exchanging Energy of Anionic/Cationic Surfactants System on the Surface of Solution[J]. Chinese Chemical Letters, 2003, 14(10): 1077-1080
Authors:Zheng Wu WANG  Dong Yang HUANG  Xi Zhang YI
Abstract:
In order to study synergism of the mixed surfactants system with molecular exchanging energy (E), the Lennard-Jones formula has been firstly introduced to evaluate the E of the mixed system, CH3(CH2)nOSO 3 /CH3(CH2)nN+(CH3)3 directly from their molecular structure. The comparison of the calculated and the observed results showed that this method is practical.
Keywords:Surfactant   molecule exchanging energy   dimensional crystal model.
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