ortho-metallation reactions involving some triphenyl phosphite complexes of osmium |
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| Authors: | Eric W. Ainscough Tom A. James Stephen D. Robinson Jonathan N. Wingfield |
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| Affiliation: | Department of Chemistry, King''s College, Strand, London WC2R 2LS Great Britain |
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| Abstract: | ![]()
Osmium triphenylphosphine complexes, OsH4(PPh3)3, OsH2 (CO)(PPh3)3 and OsHCl(CO)(PPh3)3 react with triphenyl phosphite in boiling organic solvents to yield triphenyl phosphite derivatives which subsequently undergo ortho-metallation reactions. |
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