Short synthesis of the CDEF ring system of lactonamycin |
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Authors: | Kelly T Ross Xu Dongcheng Martínez Gabriel Wang Haixia |
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Affiliation: | E. F. Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, USA. ross.kelly@bc.edu |
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Abstract: | [reaction: see text]. A synthesis of the CDEF fragment of lactonamycin is achieved in eight steps (six pots) from the known and readily available anhydride 4 via a Diels-Alder reaction between tricycle 13 and 2,3-dimethylbenzoquinone. |
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