Synthesis of water-soluble Mo(0) tetracarbonyl complexes containing nitrogen donor ligands and polymerization of methyl methacrylate |
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Authors: | Ayfer Menteş Murat Emre Hanhan |
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Institution: | (1) Department of Chemistry, Zonguldak Karaelmas University, Zonguldak, 67100, Turkey |
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Abstract: | Water-soluble Mo(0) tetracarbonyl complexes containing a α-diimine ligand have been prepared. All the complexes were characterized
by elemental, LC-MS (APCI), FT-IR, 1H-NMR, and 13C-NMR spectroscopy. The pH dependent phase transfer of these complexes was investigated. This pH dependent phase transfer
was accomplished over 10 times with no evidence of complex decomposition. Their catalytic activities on methyl methacrylate
polymerization were determined. |
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Keywords: | |
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