| 镧与β-丙氨酸配合物{[La2(β-ala)6(H2O)4](ClO4)6·H2O}n的合成及晶体结构 |
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| 引用本文： | 马录芳,梁福沛,覃海错,张漫波,胡瑞祥,郁开北.镧与β-丙氨酸配合物{[La2(β-ala)6(H2O)4](ClO4)6·H2O}n的合成及晶体结构[J].无机化学学报,2002,18(2):205-208. |
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| 作者姓名： | 马录芳 梁福沛 覃海错 张漫波 胡瑞祥 郁开北 |
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| 作者单位： | 广西师范大学化学系,桂林 541004,广西师范大学化学系,桂林 541004,广西师范大学化学系,桂林 541004,广西师范大学化学系,桂林 541004,广西师范大学化学系,桂林 541004,中国科学院成都有机所分析测试中心,成都 610041 |
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| 基金项目： | 广西自然科学基金资助项目(No.桂自9912044). |
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| 摘 要： | The complex, {La2(β-ala)6(H2O)4](ClO4)6·H2O}n, was synthesized in aqueous solution and its crystal structure was determined by X-ray diffraction method .The crystal is triclinic with space group of .The cell pa-rameters are a=0.946(1)nm, b=1.2917(1)nm, c=2.1726(3)nm,α=76.79(1)°, β=80.85(1)°,γ=83.35(1)°, V=2.5429(5)nm3, Z=2, Dc=1.958g·cm-3.The complex is an one-dimensional infinite chain. The coordination number of lanthanum ion is nine, forming a distorted tricapped trigonal prism.
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| 关 键 词： | 镧配合物 β-丙氨酸 晶体结构 |
| 修稿时间： | 2001年6月14日 |
H2O}n |
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| MA Lu-Fang,LIANG Fu-Pei,QIN Hai-Cuo,ZHANG Man-Bo,HU Rui-Xiang and YU Kai-Bei.H2O}n[J].Chinese Journal of Inorganic Chemistry,2002,18(2):205-208. |
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| Authors: | MA Lu-Fang LIANG Fu-Pei QIN Hai-Cuo ZHANG Man-Bo HU Rui-Xiang and YU Kai-Bei |
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| Institution: | Department of Chemistry, Guangxi Normal University, Guilin 541004,Department of Chemistry, Guangxi Normal University, Guilin 541004,Department of Chemistry, Guangxi Normal University, Guilin 541004,Department of Chemistry, Guangxi Normal University, Guilin 541004,Department of Chemistry, Guangxi Normal University, Guilin 541004 and Chengdu Center of Analysis and Measurement ,Academia Sinica,Chengdu 610041 |
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