Separation of strontium from simulated waste in K2SO4/Nitrate medium containing Sr2+, Eu3+, Ce3+, Pd2+, Rh3+, Ru3+, UO 2 2+ , Fe3+, Cr3+, Ni2+, Al3+, Ca2+ and Cs+, by strongly basic anion exchanger |
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Authors: | N. El-Said A. S. Mekhael S. M. Khalifa H. F. Aly |
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Affiliation: | 1. Hot Laboratories Centre, Atomic Energy Authority, Post Code 13759, Cairo, (Egypt)
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Abstract: | In this work Strontium was separated selectively form, Pd2+, Ni2+ and Ca3+ using anionic resins of Amberlite type IRA-900 and IRA-410 from nitrate medium. The Separation of strontium by strongly basic anion exchangers IRA-410 and IRA-900 from simulated waste containing, Sr2+, Eu3+, Ce3+, Pd2+, Rh3+, Ru3+, VO2 2+, Fe3+, Cr3+, Ni2+, Al3+, Ca2+, and Cs+, in K2SO4/nitrate medium which adsorbed as strontium sulphate complex was achieved through ligand- ligan exchange. The elution of strontium carried out via “loading” the column with a solution of 0.03N EDTA in presence of 0.1N NaNO3 at pH7 where Sr2+ has low Kd value. An inductively Coubled Plasma — Optical Emission Spectrometry (ICP — OES) of ARL type model 3520, was used for elemental analysis. |
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