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New potentially environmentally friendly copolymer of styrene and maleic acid—castor oil monoester
Authors:Xamxikamar Mamat  Yonglei Wang  Wumanjiang Eli
Affiliation:1. Xinjiang Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, , Urumqi, 830011 China;2. Graduate University of the Chinese Academy of Sciences, , Beijing, 100049 China;3. Changzhou Institute of Chemistry, , Changzhou, 213164 China
Abstract:The maleic acid‐castor oil monoester (MACO) was synthesized and was used as monomer to synthesize a new potentially environmentally friendly copolymer of styrene and MACO (poly‐St/MACO) by suspension polymerization. Under the appropriate conditions, the poly‐St/MACO with yield of 81%, number average molecular weight of 44100 g/mol, and molecular weight distribution of 1.5 could be obtained. The chemical structures of the MACO and resulting copolymer were confirmed by Mass Spectrometry Infrared Spectroscopy and Nuclear Magnetic Resonance Spectroscopy H[1]. The results of thermogravimetric analysis and biodegradation test showed the poly‐St/MACO can be used as a new potentially environmentally friendly material with excellent thermal stability. Copyright © 2011 John Wiley & Sons, Ltd.
Keywords:environmentally friendly  maleic anhydride  castor oil  monoester  styrene  copolymer
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