|
|||||
|
|
2-Bromo-2-cyano-N,N-dimethylacetamide as a new brominating agent |
|
| Authors: | M. Sekiya K. Ito K. Suzuki |
| Affiliation: | Shizuoka College of Pharmacy, 2-2-1 Oshika, Shizuoka, Japan |
| Abstract: | It has been found that 2-bromo-2-cyano-N,N-dimethylacetamide is effective for monobromination at α-carbon of ketones with high selectivity. Effects of solvent and of radical initiator and scavenger are suggestive of radical mechanism. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |