New “Gabriel” syntheses of amines |
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| Authors: | J.B. Hendrickson R. Bergeron D.D. Sternbach |
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| Affiliation: | Contribution from the Edison Chemical Laboratories, Brandeis University, Waltham, MA 02154, U.S.A. |
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| Abstract: | ![]()
The Gabriel synthesis is generalized as monoalkylation of an ammonia or primary amine derivative with subsequent removal of the derivatizing group(s) from nitrogen. Two new derivatives for this purpose are introduced: phenacylsulfonamides and triflamides, with discussion of their generality and effectiveness. |
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