Preparation,structures, and reactivities of compounds with double bonding between the heavier group 5A elements |
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| Authors: | Alan H Cowley Jan E Kilduff Jonathan G Lasch Sushil K Mehrotra Nicholas C Norman Marek Pakulski |
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| Institution: | Department of Chemistry , University of Texas at Austin , Austin, Texas, 78712, U.S.A. |
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| Abstract: | Abstract The synthesis of diphosphenes (RPdbnd]PR′), phosphaarsenes (RPxydAsR′), phosphastibenes (RPdbnd]SbR′), and diarsenes (RAsdbnd]AsR′) is discussed. X-ray crystallographic studies have been performed on representative double-bonded compounds. The reactivities and coordination chemistry of selected compounds have been explored. |
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