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REACTIONS OF THE SUBSTITUTED THIOUREAS WITH PLATINUM COMPOUNDS
Authors:Jaroslav Kovác  Jolana Ková?oá
Institution:1. Department of Organic Chemistry , Slovak Technical University , 88037, Bratislava, Czechoslovakia;2. Department of Inorganic Chemistry , Slovak Technical University , 88037, Bratislava, Czechoslovakia
Abstract:Abstract

Thiourea and its derivatives easily form the complexes with compounds of CuII, FeIII, PtIV etc. By the formation of complexes as a rule redoxprocess proceeds to give an appropriate thiourea disulphide. It has been shown, that redoxprocess goes on prejudice on the derivatives of thiourea in that case when the thion-thiol tautomerism is possible.
Keywords:Cyclocondensation  bis(dialky1amino)chlorophosphine  hydrazinothiazole  tris(dialkyl-amino)phosphine  conformation  dicyclotriazaphosphole
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