Transition Metal Substituted Phosphanes: Synthesis,Reactivity and Pyramidal Inversion |
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| Authors: | W Malisch R Maisch A Meyer D Greissinger E Gross I J Colquhoun |
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| Institution: | Institut für Anorganische Chemie der Universit?t Würzburg , Am Hubland, D-8700, Würzburg, Germany |
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| Abstract: | Abstract The synthesis of transition metal substituted phosphanes C5H5(CO)2M-PPh2, C5H5(CO)2(Me3P)M-PPh2 (M dbnd] Mo, W) and C5H5(CO)(Me3P)FePPhR (R dbnd] Me, Ph) is described as well as their reactivity towards a series of electrophilic and oxidizing reagents. |
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