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STUDIES ON ORGANOPHOSPHORUS COMPOUNDS PART IX.1 THE ACTION OF Di-, TRIALKYL PHOSPHITES AND THIOL ACIDS ON SOME ENAMINOLACTONES
Authors:R. Shabana  M. M. Sidky  A. A. El-kateb  F. M. Soliman
Affiliation:National Research Centre , Dokki, Cairo, Egypt
Abstract:Abstract

Di-, and trimethylphosphites react with enaminolactone, 4, only in methanol to give N-benzoyl-3-phenyl-3-phosphonoalanine-trimethylester (7) in good yields. Diphenylphosphinodithioic acid also reacts with 4 to give N-benzoyl-3-phenylcysteine-methyl ester-diphenylphosphinodithioate (9). A mechanism is proposed to account for the formation of 7. Compatible analytical and spectroscopic results were obtained for the new compounds.
Keywords:Organosilicon(IV) complexes  thio-imines  sterilizing agents  1H NMR and 13C NMR spectra
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