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Corrected Marcus plots |
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| Authors: | Pavel A. Zagrebin Galina A. Tsirlina Renat R. Nazmutdinov Oleg A. Petrii Michael Probst | ||
| Affiliation: | (1) Department of Electrochemistry, Chemical Faculty, Moscow State University, Leninskie Gory 1-str.3, GSP-2, 119992 Moscow, Russia;(2) Kazan State Technological University, K.Marx str., 68, Kazan, 420015 Kazan, Republic Tatarstan, Russia;(3) Institute of Ions Physics, University of Innsbruck, 6020 Innsbruck, Austria | ||
| Abstract: | The advantages of corrected Marcus plots as compared to the more traditional corrected Tafel plots are discussed and illustrated by the treatment of experimental data. The procedures are proposed to avoid the uncertainties of EDL correction and to estimate the reliable values of transmission coefficient and total reorganization energy. Special emphasis is placed on the diagnostics of activationless reactions in frames of the same method. Dedicated to Professor M.A. Vorotyntsev on the occasion of his 60th birhtday.
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