Facile homogeneous hydrogenations of hindered olefins with [Ir(cod)py(PCy3)]PF6 |
| |
| Authors: | J.William Suggs S.D. Cox Robert H. Crabtree Jennifer M. Quirk |
| |
| Affiliation: | Bell Laboratories 600 Mountain Avenue Murray Hill, New Jersey 07974 USA;Department of Chemistry Yale University New Haven, Connecticut 06520 USA |
| |
| Abstract: | ![]()
The title complex readily hydrogenates a number of hindered steroidal olefin groups from the α face, without reducing ketone carbonyl groups, carbon—halogen bonds or cyclopropane rings. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
