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Synthesis of an isomer of the germacranolide isoaristolactone
Authors:Gordon L. Lange  Solomon So  Mark Lautens  Kevin Lohr
Affiliation:Guelph-Waterloo Centre for Graduate Work in Chemistry Department of Chemistry, University of Guelph, Guelph, Ontario, N1G 2W1, Canada
Abstract:
Photocycloadditlon of (+)-isoplperltenone and cyclobutene-1-carboxylic acid gives an adduct which upon reduction with NaCNBH3 followed by thermolysis yields an isomer of isoaristolactone in an overall yield of 26%.
Keywords:
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