Measuring chirality in NMR in the presence of a static electric field |
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| Authors: | Walls Jamie D Harris Robert A Jameson Cynthia J |
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| Affiliation: | Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA. jwalls@fas.harvard.edu |
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| Abstract: | ![]()
The scalar Hamiltonian of nuclear spins in the presence of a static electric field supports chirality. However, the eigenvalues of the Hamiltonian are not chiral; hence, chirality is not manifested in the usual NMR experiment. In this work, we show that the magnetization response to certain radio frequency pulse sequences exhibits chirality as well as handedness. |
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