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Silica supported perchloric acid (HClO4-SiO2): A mild,reusable and highly efficient heterogeneous catalyst for the synthesis of amidoalkyl naphthols
引用本文:Gholam Hossein Mahdavinia,;Mohammad A. Bigdeli,;Majid M. Heravi. Silica supported perchloric acid (HClO4-SiO2): A mild,reusable and highly efficient heterogeneous catalyst for the synthesis of amidoalkyl naphthols[J]. 中国化学快报, 2008, 19(10): 1171-1174. DOI: 10.1016/j.cclet.2008.06.048
作者姓名:Gholam Hossein Mahdavinia,  Mohammad A. Bigdeli,  Majid M. Heravi
作者单位:a Department of Chemistry, IslamicAzad University-Marvdasht Branch, Marvdasht, Iran;b Faculty of Chemistry, Teacher Training University, 49 Mofateh Street, Tehran, Iran;c Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran
基金项目:We are grateful for the financial support of this work by the National Natural Science Foundation of China (No. 20343005, 20473107, 20673130, and 20773147).
摘    要:
An efficient and direct procedure has been developed for the preparation of amidoalkyl naphthols by a one-pot condensation of aryl aldehydes, 2-naphthol and urea or amides, in the presence of HClO4-SiO2 as a heterogeneous catalyst. The reactions were carried out under reflux and solvent-free conditions. The present methodology offers several advantages such as excellent yields, simple procedure, easy work-up and ecofriendly reaction condition. The catalyst is easily prepared, stable, reusable and efficient under the reaction conditions.

关 键 词:HClO4-SiO2  二氧化硅  多相催化反应  多元反应

Silica supported perchloric acid(HClO_4-SiO_2):A mild,reusable and highly efficient heterogeneous catalyst for the synthesis of amidoalkyl naphthols
Gholam Hossein Mahdavinia Mohammad A. Bigdeli Majid M. Heravi. Silica supported perchloric acid(HClO_4-SiO_2):A mild,reusable and highly efficient heterogeneous catalyst for the synthesis of amidoalkyl naphthols[J]. Chinese Chemical Letters, 2008, 19(10): 1171-1174. DOI: 10.1016/j.cclet.2008.06.048
Authors:Gholam Hossein Mahdavinia Mohammad A. Bigdeli Majid M. Heravi
Affiliation:a Department of Chemistry, IslamicAzad University-Marvdasht Branch, Marvdasht, Iran;b Faculty of Chemistry, Teacher Training University, 49 Mofateh Street, Tehran, Iran;c Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran
Abstract:
An efficient and direct procedure has been developed for the preparation of amidoalkyl naphthols by a one-pot condensation of aryl aldehydes,2-naphthol and urea or amides,in the presence of HClO_4-SiO_2 as a heterogeneous catalyst.The reactions were carried out under reflux and solvent-free conditions.The present methodology offers several advantages such as excellent yields, simple procedure,easy work-up and ecofriendly reaction condition.The catalyst is easily prepared,stable,reusable and efficient under the reaction conditions.
Keywords:One-pot  HClO_4-SiO_2  Heterogeneous catalyst  Amidoalkyl naphthol  Multicomponent reaction
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