Synthesis and structure of N-(2-silatranylethyl)pyrazoles |
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Authors: | V. D. Sheludyakov N. E. Kuz’mina A. M. Abramkin A. A. Korlyukov D. E. Arkhipov S. V. Loginov D. A. Cheshkov P. A. Storozhenko |
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Affiliation: | 1.State Research Institute of Chemistry and Technology of Organometallic Compounds,Moscow,Russia;2.Medical Equipment Scientific Appraisal Center,Moscow,Russia;3.Nesmeyanov Institute of Organometallic Compounds,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | Organosilicon pyrazole derivatives containing a 2-siltranylethyl fragment on the nitrogen atom were synthesized, and their structural and stereoelectronic parameters were determined by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy. The nature of interaction between the pyrazole and silatrane fragments was studied. |
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