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Konformationen diastereoisomererBis-(alkylaryl)-ether
Authors:C. R. Noe  C. Miculka  H. VÖllenkle
Affiliation:(1) Christian Doppler Laboratorium für Chemie chiraler Verbindungen: Chemische Synthese, Institut für Pharmazeutische Chemie, D-60439 Frankfurt, Deutschland;(2) Institut für Mineralogie, Kristallographie und Strukturchemie, Technische Universität Wien, A-1060 Wien, Österreich
Abstract:Summary X-ray-analysis of the meso-ether2 showed the existence of two bridged species in the unit cell besides the expected molecule. The additional bonds between the 9- and 10-positions of the anthracene moieties were extraordinarily long. This fact leads to conclusions on the reactive behaviour of alkylaryl carbinoles upon acid-catalysed etherification.
Keywords:Ethers, diastereomeric    /content/w1l20256475h6853/xxlarge960.gif"   alt="  pgr"   align="  BASELINE"   BORDER="  0"  >-  /content/w1l20256475h6853/xxlarge960.gif"   alt="  pgr"   align="  BASELINE"   BORDER="  0"  >-Interaction, aromatic  Cycloaddition, intramolecular
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