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Decyclization of chiorocyclohexanone hydroperoxides under the action of ferrous salts |
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| Authors: | E K Starostin V V Gushchin A V Ignatenko A V Aleksandrov G L Nikishin |
| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
| Abstract: | The decomposition of 2-chloro-, 2,2-dichloro-, and 2,6-dichloro-substituted cyclohexanone hydroperoxides on treatment with ferrous chloride and sulfate to give chloro-substituted aliphatic acids was investigated. A method for the synthesis of 2,6,6-trichlorohexanoic and 2,6,7,11-tetrachlorododecane-1,12-dioic acids was elaborated.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 143–146, January, 1996. |
| Keywords: | hydrogen peroxide hydroperoxides cyclohexanone decyclization chlorocarboxylic acids ferrous salts |
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