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| 配合物[Zn(tren)(H-SSA)]的合成、晶体结构及表征 | |
| 引用本文： | 马卫兴,钱保华,高健,许兴友,陆路德,杨绪杰,汪信,宋海斌.配合物[Zn(tren)(H-SSA)]的合成、晶体结构及表征[J].无机化学学报,2005,21(4):612-616. |
| 作者姓名： | 马卫兴 钱保华 高健 许兴友 陆路德 杨绪杰 汪信 宋海斌 |
| 作者单位： | 1. 南京理工大学材料化学实验室,南京,210094;淮海工学院化学工程系,连云港,222005 2. 南京理工大学材料化学实验室,南京,210094 3. 南开大学化学学院,天津,300071 |
| 基金项目： | 国家自然科学基金资助项目(No.50373019)，江苏省自然科学基金资助项目(No.BK2003097)，江苏省高校自然科学研究计划资助项目(No.01KJB150011)，淮海工学院学科基金资助项目(No.XK200310)。 |
| 摘 要： | A new mixed complex Zn(tren) (H-SSA)] was synthesized based on the reaction of ZnO,5-sulfosalicylic acid and tren in water-methanol mixed solvents where tren was tris(2-aminoethyl)amine for the first time. The structure of the mixed complex was characterized by elemental analysis, IR, 1H NMR and thermal analysis. The crystal structure of the complex was also determined by X-ray single crystal diffraction. Its crystal belongs to trigonal system with space group P31, a=1.109 67(18) nm, b=1.109 67(18) nm, c=1.236 8(4) nm, V=1.318 9(5) nm3; Dc=1.616 g·cm-3; Z=3; F(000)=666; μ=1.553 mm-1. CCDC: 253908. |
| 关 键 词： | Zn(Ⅱ)配合物 谱学表征 晶体结构 |
| 文章编号： | 1001-4861(2005)04-0612-05 |
| 收稿时间： | 2004/9/27 0:00:00 |
| 修稿时间： | 2004年9月27日 |
Synthesis, Crystal Structure and Spectral Characterization of the Complex [Zn(Tren)(H-SSA)] |
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| MA Wei-Xing,QIAN Bao-Hu,GAO Jian,XU Xing-You,LU Lu-De,YANG Xu-Jie,WANG Xin and SONG Hai-Bin.Synthesis, Crystal Structure and Spectral Characterization of the Complex [Zn(Tren)(H-SSA)][J].Chinese Journal of Inorganic Chemistry,2005,21(4):612-616. | |
| Authors: | MA Wei-Xing QIAN Bao-Hu GAO Jian XU Xing-You LU Lu-De YANG Xu-Jie WANG Xin and SONG Hai-Bin |
| Institution: | Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094;Dept. of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094;Dept. of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094;Dept. of Chemical Technology, Huaihai Institute of Technology, Lianyungang 222005,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 and College of Chemistry, Nankai University, Tianjin 300071 |
| Abstract: | |
| Keywords: | Zn complex spectral characterization crystal structure |
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