Hybrid Organic-Inorganic Copolymers Based on Oxo-Hydroxo Organotin Nanobuilding Blocks |
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Authors: | F. Ribot F. Banse C. Sanchez M. Lahcini B. Jousseaume |
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Affiliation: | (1) Chimie de la Matière Condensée (URA 1466), Univ. P. et M. Curie, 4, place Jussieu, Paris, France;(2) Chimie Organique et Organométallique (URA 35), Univ. Bordeaux I, 351, cours de la Libération, Talence, France |
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Abstract: | Hybrid organic-inorganic copolymers have been prepared following the nano-building blocks approach. The oxo-hydroxo butyltin macro-cation, {(BuSn)12O14(OH)6}2+, which is prepared by hydrolysis of butyltin triisopropoxide, is first functionalized by anchoring onto it methacrylate groups through electrostatic interactions. Then, to turn these isolated nano-building blocks into hybrid copolymers, they were assembled by initiating the organic polymerization of the methacrylate functions.13C and119Sn NMR, in the solid state, and QELS evidences of the formation of hybrid organic-inorganic copolymers are reported. |
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Keywords: | hybrid copolymers nano-building blocks oxo-hydroxo organotin clusters 119Sn-NMR methacrylate |
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