A stereocontrolled synthesis of <math><mtext>Z</mtext></math> and <math><mtext>E</mtext></math> terminal dienes from pinacol <math><mtext>E</mtext></math>-1-trimethylsilyl-1-propene-3-boronate期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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A stereocontrolled synthesis of $Z$ and $E$ terminal dienes from pinacol $E$ -1-trimethylsilyl-1-propene-3-boronate

Authors:	David Jieh Shyh Tsai Donald S Matteson

Institution:	Department of Chemistry, Washington State University, Pullman, Washington 99164 U.S.A.

Abstract:	Pinacol $E$ -1-trimethylsilyl-1-propene-3-boronate reacts with aldehydes to form (±)-( $R$ , $S$ )-3-trimethylsilyl-4-hydroxy-1-alkenes, which can be deoxysilylated stereoselectively to either 98% $Z$ or 99% $E$ 1,3-dienes, including the separate components of the red bollworm moth pheromone.

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