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一种节状纳米碳纤维的CVD生长
引用本文:杨杭生,徐铸德,卢筱楠,吴国涛,王淼,李文铸.一种节状纳米碳纤维的CVD生长[J].化学物理学报(中文版),2000,13(3):324-328.
作者姓名:杨杭生  徐铸德  卢筱楠  吴国涛  王淼  李文铸
作者单位:杨杭生,徐铸德(浙江大学化学系杭州310027);卢筱楠,吴国涛,王淼,李文铸(浙江大学物理系杭州310027)  
基金项目:浙江省自然科学基金  
摘    要:介绍了以发泡Ni为催化剂、用CVD法生长节状纳米碳纤维的工艺过程,讨论了工艺参数对生成样品的产率和形貌的影响,同时还探讨了该样品的生长机理。认为催化剂的不同晶面分别有利于烃类气体的吸附解离或碳的沉积,因此催化剂颗粒的原始形貌影响了不同开貌的碳纤维生长。

关 键 词:节状纳米碳纤维  催化剂  发泡Ni

Synthesis of Segmented Carbon Filaments by CVD
Yang Hangsheng,Xu Zhude,Lu Xiaonan,Wu Guotao,Wang Miao,Li Wenzhu.Synthesis of Segmented Carbon Filaments by CVD[J].化学物理学报(中文版),2000,13(3):324-328.
Authors:Yang Hangsheng  Xu Zhude  Lu Xiaonan  Wu Guotao  Wang Miao  Li Wenzhu
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Abstract:Segmented carbon filaments were prepared by pyrolysis of acetylene using foam Ni as the catalyst.The effects of reaction conditions on the yield and the morphology of the product were studied.The growth mechanism of the sample is discussed.It is suggested that the different micro-crystal faces of the catalyst favor either the adsorption and dissociation of gaseous hydrocarbon or the carbon deposition respectively.So the original shapes of the catalyst grains have affected the product morphology.
Keywords:CVD  Segmented carbon nano filaments  Catalyst  Foam Ni  CVD
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