Reactions of organolithium and grignard reagents with the cyclopentadienyliron tricarbonyl cation and its derivatives |
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| Authors: | MY Darensbourg |
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| Institution: | Department of Chemistry, State University of New York at Buffalo, Buffalo, New York, 14214 U.S.A. |
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| Abstract: | Reactions of CH3Li, C6H5Li, and C6H5CH2MgCl with (C5H5)Fe(CO)2Y]+-B(C6H5)4]− Y Co, P(C6H5)3, and CS] have been investigated. The organolithium reagents used act either as reducing agents or as nucleophilic reagents towards the cyclopentadienyliron tricarbonyl cation and its thiocarbonyl analogue. Benzyl-magnesium chloride reacts with the cyclopentadienyl ring of (C5H5)Fe(CO)3]+ and (C5H5)Fe(CO)2P(C6H5)3]+ producing neutral cyclopentadiene complexes. |
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