Through-bond vs through-space interactions : The stabilization of carbonium ions |
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| Authors: | T.D. Goldman |
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| Affiliation: | Department of Chemistry, New York University, University Heights, Bronx, New York 10453 U.S.A. |
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| Abstract: | The solvolysis technique is suggested as an investigational tool for the possible opposing effects of through-bond and through-space orbital interactions. Existing data indicate, however, that such effects are negligible. A rationalization of the results is presented. |
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