CO2 laser induced reactions of trichloroethylene |
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Authors: | Kwang Yul Choo Tai Jong Kang Q.Won Choi |
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Affiliation: | Department of Chemistry, Seoul national, University, Seoul 151, Korea |
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Abstract: | The pressure and laser-power dependence of the product distributions in the TEA CO2 laser induced decomposition of trichloroethylene were studied. At moderate pressures molecular elimination of HCl to give CClCCl via intermolecular energy transfer was found to be the major reaction path. At low pressures a pure laser-induced CCl bond fission to give CHCCl was found to be the primary, reaction step. |
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