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CO2 laser induced reactions of trichloroethylene
Authors:Kwang Yul Choo  Tai Jong Kang  Q.Won Choi
Affiliation:Department of Chemistry, Seoul national, University, Seoul 151, Korea
Abstract:The pressure and laser-power dependence of the product distributions in the TEA CO2 laser induced decomposition of trichloroethylene were studied. At moderate pressures molecular elimination of HCl to give CClCCl via intermolecular energy transfer was found to be the major reaction path. At low pressures a pure laser-induced CCl bond fission to give CHCCl was found to be the primary, reaction step.
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