Real-time multiphoton ionization detection of iodine atoms produced by infrared multiphoton dissociation of perfluoroalkyl iodides |
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| Authors: | P.A. Hackett P. John M. Mayhew D.M. Rayner |
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| Affiliation: | Laser Chemistry Group Division of Chemistry, National Research Council, 100 Sussex Drive, Ottawa, Ontario, Canada K1A 0R6 |
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| Abstract: | We report the direct detection of iodine atoms following infrared multiphoton dissociation of perfluoroalkyl iodides. The technique, three-photon resonant two-photon ionization, shows great promise as an actinometer for primary dissociation yield in IRMPD. |
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