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Revised analysis of the structure of the v1 band of methane |
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| Authors: | H Frunder D Illig H Finsterhölzl HW Schrōtter B Lavorel G Roussel JC Hilico JP Champion G Pierre G Poussigue E Pascaud |
| Institution: | Sektion Physik der LMU Mūnchen, Schellingstrasse 4, D-8000 Munich 40, Federal Republic of Germany;Laboratoire de Spectronomie Moléculaire, Université de Dijon, 6, Boulevard Gabriel, F-21100 Dijon, France;Laboratoire d''Infrarouge. Université de Paris-Sud, Batiment 350, F-91405 Orsay Cedex, France |
| Abstract: | The CARS spectrum of the v1 band of 12CH4 at a pressure of 14 mbar was recorded using cw excitation in the cavity of a ring argon ion laser. The analysis of the intensity profile of the obarred spectrum led to the detection of inconsistencies with the hitherto proposed calculated positions of transitions with J = 7 to J = 10 and to a relocation of the corresponding lines. |
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