| Synthesis and Cleavage Studies of a 1,2-Dioxolane-type Peroxide |
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| 作者姓名： | 刘鹤华 金红霞 伍贻康 |
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| 作者单位： | StateKeyLaboratoryofBio-organic＆NaturalProductsChemistry,ShanghaiInstituteofOrganicChemistry,Chi-neseAcademyofSciences,Shanghai200032,China |
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| 基金项目： | the National Natural Science Foundation (Nos. 20025207, 20272071, 20372075 and 20321202), the Qinghaosu Science and Technology Foundation, the Chinese Academy of Sciences (KGCX2-SW-209) and the Major State Basic Research Develop |
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| 摘 要： | A 1,2]dioxolane-type peroxide was synthesized and tested for its cleavage behavior with Fe^2 -cysteinate as a simple model of biological redox species. No S-alkylation product was observed.
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| 关 键 词： | 合成 分解反应 有机过氧化物 S烃化产物 |
Synthesis and Cleavage Studies of a 1,2-Dioxolane-type Peroxide |
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| LIU,He-Hua JIN,Hong-Xia WU,Yi-Kang State Key Laboratory of Bio-organic & Natural Products Chemistry.Synthesis and Cleavage Studies of a 1,2-Dioxolane-type Peroxide[J].Chinese Journal of Chemistry,2004,22(9):1029-1033. |
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| Authors: | LIU He-Hua JIN Hong-Xia WU Yi-Kang State Key Laboratory of Bio-organic & Natural Products Chemistry |
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| Institution: | LIU,He-Hua JIN,Hong-Xia WU,Yi-Kang State Key Laboratory of Bio-organic & Natural Products Chemistry,Shanghai Institute of Organic Chemistry,Chi-nese Academy of Sciences,Shanghai 200032,China |
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| Abstract: | A 1,2]dioxolane-type peroxide was synthesized and tested for its cleavage behavior with Fe2+-cysteinate as a simple model of biological redox species. No S-alkylation product was observed. |
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| Keywords: | cyclic peroxide artemisinin free radical cleavage mechanism |
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