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反相微乳液法制备尺寸可调的高荧光碳量子点(英文)
引用本文:董英鸽,杨金龙,丁艳丽,魏志佳,胡胜亮.反相微乳液法制备尺寸可调的高荧光碳量子点(英文)[J].发光学报,2015,36(2):157-162.
作者姓名:董英鸽  杨金龙  丁艳丽  魏志佳  胡胜亮
作者单位:1. 中北大学 材料科学与工程学院, 山西 太原 030051; 2. 清华大学 新型陶瓷与精细工艺国家重点实验室, 北京 100084
摘    要:在反相微乳液体系中,以抗坏血酸作为碳源制备具有高强度荧光的碳量子点。实验中通过调整水和表面活性剂的量比实现对碳量子点尺寸大小的控制,利用十六烷基胺修饰碳量子点。当激发波长为360 nm时,碳量子点的量子产率最高为47%。当水和表面活性剂的量比从20增加到50时,碳量子点的尺寸也随之而增大。

关 键 词:碳量子点  反相微乳液  尺寸可调
收稿时间:2014-10-16

Size-controllable Synthesis of Highly Fluorescent Carbon Quantum Dots in A Reverse Microemusion
DONG Ying-ge,YANG Jin-long,DING Yan-li,WEI Zhi-jia,HU Sheng-liang.Size-controllable Synthesis of Highly Fluorescent Carbon Quantum Dots in A Reverse Microemusion[J].Chinese Journal of Luminescence,2015,36(2):157-162.
Authors:DONG Ying-ge  YANG Jin-long  DING Yan-li  WEI Zhi-jia  HU Sheng-liang
Institution:1. School of Materials Science and Engineering, North University of China, Taiyuan 030051, China; 2. State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084, China
Abstract:Highly luminescent carbon quantum dots (CQDs) were prepared by using L-ascorbic acid as a carbon source derived from reverse microemulsion. This method could control the CQDs size directly by adjusting water-surfactant molar ratio without other procedure. Hexadecylamine was used to functionize CQDs. The synthesized CQDs had high quantum yield of maximum 47% at the 360 nm excitation wavelength and the particle size could be tuned by changing the molar ratio of the water to surfactant from 20 to 50.
Keywords:CQDs  reverse microemulsion  size tunability
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