| Exchange Interaction of a Novel Heterospin Polynuclear Complex Containing Transition Metals and Imino Nitroxide Radicals: {[(CuL)Ni(IM-2Py)_2](ClO_4)_2}_2·2H_2O |
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| 引用本文： | 刘志亮,李立存,廖代正,姜宗慧,阎世平.Exchange Interaction of a Novel Heterospin Polynuclear Complex Containing Transition Metals and Imino Nitroxide Radicals: {[(CuL)Ni(IM-2Py)_2](ClO_4)_2}_2·2H_2O[J].中国化学,2003(2). |
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| 作者姓名： | 刘志亮 李立存 廖代正 姜宗慧 阎世平 |
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| 作者单位： | Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemistry，Nankai University，Tianjin 300071，China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (Nos .2 0 1710 2 5and 90 10 10 2 8) |
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| 摘 要： | IntroductionThemajorresearchaimsinthefieldofmolecularmag netismareontheonehandthedesignofmolecularassembliesthatexhibitaspontaneousmagnetizationandontheotherhandtherationalizationofmagnetostructuralcorrelation .1Polynuclearmacrocycliccomplexesandnitroxideradicalmetalliccomplexesaretwoactivefieldsofresearchfordesign ingandsynthesizingnewmagneticmaterials.2 6Polynuclearmacrocycliccomplexescontainingmul tiatomicbridgesuchasphenolateoxygen ,oxamidoandoxi amtogroupshavebeenconsiderablyinvestigated…
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