Iridium-catalyzed enantioselective hydrogenation of alpha,beta-unsaturated carboxylic acids |
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| Authors: | Li Shen Zhu Shou-Fei Zhang Can-Ming Song Song Zhou Qi-Lin |
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| Affiliation: | State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China. |
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| Abstract: | A highly efficient iridium-catalyzed hydrogenation of alpha,beta-unsaturated carboxylic acids has been developed by using chiral spiro-phosphino-oxazoline ligands, affording alpha-substituted chiral carboxylic acids in exceptionally high enantioselectivities and reactivities. |
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