| 硫酸盐还原菌的含硫代谢产物在加速碳钢腐蚀中的作用 |
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| 引用本文： | 李付绍,安茂忠,刘光洲,段东霞.硫酸盐还原菌的含硫代谢产物在加速碳钢腐蚀中的作用[J].无机化学学报,2009,25(1):13-18. |
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| 作者姓名： | 李付绍 安茂忠 刘光洲 段东霞 |
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| 作者单位： | 1. 哈尔滨工业大学化工学院,哈尔滨,150001
2. 海洋腐蚀与防护国防科技重点实验室,青岛,266071 |
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| 基金项目： | 青岛市科技局资助项目 |
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| 摘 要： | 应用电化学阻抗谱(EIS)研究了硫酸盐还原菌(SRB)对碳钢腐蚀过程的促进作用，应用稳态极化法研究了SRB代谢硫化物对碳钢阳极活性溶解的增强作用。研究结果表明，代谢硫化物通过对铁的吸附增强了碳钢阳极活性溶解，因为依据吸附态E-pH图可知，在很宽的电位范围和pH值范围内，硫在铁上都能以稳定的吸附态存在。吸附态硫提升了碳钢表面铁原子能量，使铁阳极溶解所需活化能降低，从而增强其阳极溶出过程。
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| 关 键 词： | 硫酸盐还原菌 EIS 阳极活性溶解 吸附态E-pH图 Tafel斜率 |
Roles of Sulfur-containing Metabolites by SRB in Accelerating Corrosion of Carbon Steel |
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| LI Fu-Shao,AN Mao-Zhong,LIU Guang-Zhou and DUAN Dong-Xia.Roles of Sulfur-containing Metabolites by SRB in Accelerating Corrosion of Carbon Steel[J].Chinese Journal of Inorganic Chemistry,2009,25(1):13-18. |
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| Authors: | LI Fu-Shao AN Mao-Zhong LIU Guang-Zhou and DUAN Dong-Xia |
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| Institution: | Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001,Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001,State Key Laboratory for Marine Corrosion and Protection, Qingdao, Shandong 266071 and State Key Laboratory for Marine Corrosion and Protection, Qingdao, Shandong 266071 |
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| Abstract: | Effects of sulfate-reducing bacteria(SRB) activities on the acceleration of corrosion of carbon steel were studied by EIS and the role of sulfur-containing metabolites by SRB in enhancing the anodic active dissolution of carbon steel was investigated by steady-state polarization technique. The results show that sulfur-containing metabolites in the form of adsorbed sulfur on iron enhance the anodic active dissolution of carbon steel. The adsorbed sulfur raises the energy of surface iron atoms of carbon steel, reduces the necessary activation energy for their dissolution from metal matrix and thus enhancing the anodic active dissolution. |
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| Keywords: | sulfate-reducing bacterium (SRB) EIS anodic active dissolution E-pH diagrams for adsorbed species Tafel slope |
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