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利用太赫兹时域光谱技术对环三亚甲基三硝胺(RDX)振动谱的研究
引用本文:冯瑞姝,李微微,周庆莉,牧凯军,张亮亮,张存林.利用太赫兹时域光谱技术对环三亚甲基三硝胺(RDX)振动谱的研究[J].应用光学,2009,30(6):907-910.
作者姓名:冯瑞姝  李微微  周庆莉  牧凯军  张亮亮  张存林
作者单位:1.大庆师范学院物理系,黑龙江大庆163712;
2.首都师范大学物理系北京市太赫兹波谱与成像重点实验室,北京100048
摘    要: 针对爆炸物及其相关成分的感测科学和技术对于国土安全和国家防御有着至关重要的地位,对单质炸药环三亚甲基三硝胺(RDX)进行了太赫兹(THz)谱的实验测量和理论分析。利用太赫兹时域光谱技术(THz-TDS)给出了这些炸药样品在0.2THz~2.5THz范围内的折射率和吸收系数。利用密度泛函理论进行的理论模拟与实验结果符合较好。结果发现,单质炸药RDX具有特征吸收峰,利用THz-TDS技术可以对单质炸药进行检测和识别。

关 键 词:太赫兹时域光谱  爆炸物  密度泛函
收稿时间:2009/3/5

Vibrational spectrum of RDX investigated with terahertz time-domain spectroscopy
FENG Rui-shu,LI Wei-wei,ZHOU Qing-li,MU Kai-jun,ZHANG Liang-liang,ZHANG Cun-lin.Vibrational spectrum of RDX investigated with terahertz time-domain spectroscopy[J].Journal of Applied Optics,2009,30(6):907-910.
Authors:FENG Rui-shu  LI Wei-wei  ZHOU Qing-li  MU Kai-jun  ZHANG Liang-liang  ZHANG Cun-lin
Institution:1.Department of Physics, Daqing Normal University, Daqing 163712, China; 2. Beijing Key Lab for
 Terahertz Spectroscopy and Imaging, Department of Physics, Capital Normal University, Beijing 100048, China
Abstract:Experimental and theoretical investigations on the vibration spectrum of Cyclotrimethylene-trinitramine(RDX) in the region of 0.2~2.5 terahertz are presented. The refractive index and absorption coefficient of an explosive sample were measured by terahertz time-domain spectroscopy. The theoretical simulation according to density functional theory (DFT) is in agreement with the experimental data. The obtained results indicate that the single chemical compound explosive RDX has a characteristic absorption peak, and the single chemical compound explosive can be tested and identified with THz-TDS technology.
Keywords:terahertz time-domain spectrum  single chemical compound explosive  density function theory
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