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Formation of a surface covalent organic framework based on polyester condensation
Authors:Marele Antonela C  Mas-Ballesté Rubén  Terracciano Luigi  Rodríguez-Fernández Jonathan  Berlanga Isadora  Alexandre Simone S  Otero Roberto  Gallego José M  Zamora Félix  Gómez-Rodríguez José M
Affiliation:Dpto. de Física de la Materia Condensada, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
Abstract:The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.
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